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Information card for entry 7117818
Preview
Coordinates | 7117818.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C25 H47 B N O3 P2 Rh |
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Calculated formula | C25 H47 B N O3 P2 Rh |
SMILES | C(C)[P](CC)(CC)[Rh](C#[O])(N(c1ccccc1)B1OC(C(C)(C)O1)(C)C)[P](CC)(CC)CC |
Title of publication | Remarkable reactivity of a rhodium(I) boryl complex towards CO2 and CS2: isolation of a carbido complex |
Authors of publication | Sabrina I. Kallane; Thomas Braun; Michael Teltewskoi; Beatrice Braun; Roy Herrmann; Reik Laubenstein |
Journal of publication | Chem.Commun. |
Year of publication | 2015 |
Journal volume | 51 |
Pages of publication | 14613 |
a | 9.0037 ± 0.0011 Å |
b | 11.2268 ± 0.0013 Å |
c | 15.1421 ± 0.0016 Å |
α | 83.982 ± 0.005° |
β | 80.95 ± 0.004° |
γ | 82.455 ± 0.005° |
Cell volume | 1492.9 ± 0.3 Å3 |
Cell temperature | 150 ± 2 K |
Ambient diffraction temperature | 150 ± 2 K |
Number of distinct elements | 7 |
Space group number | 1 |
Hermann-Mauguin space group symbol | P 1 |
Hall space group symbol | P 1 |
Residual factor for all reflections | 0.0669 |
Residual factor for significantly intense reflections | 0.049 |
Weighted residual factors for significantly intense reflections | 0.1114 |
Weighted residual factors for all reflections included in the refinement | 0.1218 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.016 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
For the version history of this entry, please navigate to main COD server.
The link is: https://www.crystallography.net/7117818.html
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Users of the data should acknowledge the original authors of the
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