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Information card for entry 7117927
Preview
Coordinates | 7117927.cif |
---|---|
Original paper (by DOI) | HTML |
Formula | C20 H38 Fe2 O6 P2 Si2 |
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Calculated formula | C20 H38 Fe2 O6 P2 Si2 |
SMILES | C(C)[Si]1(CC)[Fe]([P](C)(C)C)(C#[O])(C#[O])(C#[O])[Si](CC)(CC)[Fe]1([P](C)(C)C)(C#[O])(C#[O])C#[O] |
Title of publication | 1,2-Halosilane vs. 1,2-alkylborane elimination from (boryl)(silyl) complexes of iron: switching between borylenes and silylenes just by changing the alkyl group |
Authors of publication | Holger Braunschweig; Rian D. Dewhurst; Krzysztof Radacki; Benedikt Wennemann; Qing Ye |
Journal of publication | Chem.Commun. |
Year of publication | 2015 |
Journal volume | 51 |
Pages of publication | 15465 |
a | 10.1597 ± 0.0016 Å |
b | 12.9 ± 0.002 Å |
c | 10.7901 ± 0.0018 Å |
α | 90° |
β | 105.385 ± 0.005° |
γ | 90° |
Cell volume | 1363.5 ± 0.4 Å3 |
Cell temperature | 100 ± 2 K |
Ambient diffraction temperature | 100 ± 2 K |
Number of distinct elements | 6 |
Space group number | 14 |
Hermann-Mauguin space group symbol | P 1 21/n 1 |
Hall space group symbol | -P 2yn |
Residual factor for all reflections | 0.0292 |
Residual factor for significantly intense reflections | 0.0244 |
Weighted residual factors for significantly intense reflections | 0.0634 |
Weighted residual factors for all reflections included in the refinement | 0.066 |
Goodness-of-fit parameter for all reflections included in the refinement | 1.05 |
Diffraction radiation wavelength | 0.71073 Å |
Diffraction radiation type | MoKα |
Has coordinates | Yes |
Has disorder | No |
Has Fobs | No |
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The link is: https://www.crystallography.net/7117927.html
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