Information card for entry 7118718

Structure parameters

• Formula: C18 H21 Br N2 O2 Si
• Calculated formula: C18 H19.5 Br N2 O2 Si
• Title of publication: Asymmetric sequential Au(i)/chiral tertiary amine catalysis: an enone-formation/cyanosilylation sequence to synthesize optically active 3-alkenyloxindoles from diazooxindoles.
• Authors of publication: Zhao, Yu-Lei; Cao, Zhong-Yan; Zeng, Xing-Ping; Shi, Jia-Meng; Yu, Yi-Hua; Zhou, Jian
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 20
• Pages of publication: 3943 - 3946
• a: 6.623 ± 0.002 Å
• b: 8.437 ± 0.003 Å
• c: 17.92 ± 0.006 Å
• α: 88.636 ± 0.007°
• β: 88.061 ± 0.007°
• γ: 85.928 ± 0.007°
• Cell volume: 998 ± 0.6 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1063
• Residual factor for significantly intense reflections: 0.0881
• Weighted residual factors for significantly intense reflections: 0.2618
• Weighted residual factors for all reflections included in the refinement: 0.2704
• Goodness-of-fit parameter for all reflections included in the refinement: 1.082
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No