Information card for entry 7119146

Structure parameters

• Common name: ALMX88
• Formula: C51 H42 F10 N2 Pt Zn
• Calculated formula: C51 H42 F10 N2 Pt Zn
• SMILES: c1ccc2ccc3ccc[n]4c3c2[n]1[Pt]4(c1ccc(cc1)C(C)(C)C)(c1ccc(cc1)C(C)(C)C)[Zn](c1c(c(c(c(c1F)F)F)F)F)c1c(c(c(c(c1F)F)F)F)F.c1(ccccc1)C
• Title of publication: Lewis acid-base interactions between platinum(II) diaryl complexes and bis(perfluorophenyl)zinc: strongly accelerated reductive elimination induced by a Z-type ligand
• Authors of publication: Allegra L. Liberman-Martin; Daniel S. Levine; Micah S. Ziegler; Robert G. Bergman; T. Don Tilley
• Journal of publication: Chem.Commun.
• Year of publication: 2016
• Journal volume: 52
• Pages of publication: 7039
• a: 12.995 ± 0.0013 Å
• b: 16.7483 ± 0.0016 Å
• c: 21.185 ± 0.002 Å
• α: 90°
• β: 106.136 ± 0.002°
• γ: 90°
• Cell volume: 4429.1 ± 0.7 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0355
• Residual factor for significantly intense reflections: 0.0312
• Weighted residual factors for significantly intense reflections: 0.0722
• Weighted residual factors for all reflections included in the refinement: 0.0747
• Goodness-of-fit parameter for all reflections included in the refinement: 1.156
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No