Information card for entry 7119223

Structure parameters

• Formula: C32 H56 Cl Ge N2 P2 Rh
• Calculated formula: C32 H56 Cl Ge N2 P2 Rh
• SMILES: [Rh]1234([Ge]5(Cl)N(c6c(N5C[P](C(C)(C)C)C(C)(C)C)cccc6)C[P]1(C(C)(C)C)C(C)(C)C)[CH]1=[CH]2CC[CH]3=[CH]4CC1
• Title of publication: Synthesis and initial transition metal chemistry of the first PGeP pincer-type germylene.
• Authors of publication: Álvarez-Rodríguez, Lucía; Brugos, Javier; Cabeza, Javier A.; García-Álvarez, Pablo; Pérez-Carreño, Enrique; Polo, Diego
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2017
• Journal volume: 53
• Journal issue: 5
• Pages of publication: 893 - 896
• a: 14.5188 ± 0.0002 Å
• b: 17.9914 ± 0.0002 Å
• c: 13.3164 ± 0.0002 Å
• α: 90°
• β: 92.922 ± 0.001°
• γ: 90°
• Cell volume: 3473.9 ± 0.08 ų
• Cell temperature: 151 ± 2 K
• Ambient diffraction temperature: 151 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.035
• Residual factor for significantly intense reflections: 0.0306
• Weighted residual factors for significantly intense reflections: 0.076
• Weighted residual factors for all reflections included in the refinement: 0.0791
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No