Information card for entry 7121440

Structure parameters

• Chemical name: Mo(silox)2O2
• Formula: C24 H54 Mo O10 Si2
• Calculated formula: C24 H54 Mo O10 Si2
• Title of publication: Silica-supported isolated molybdenum di-oxo species: formation and activation with organosilicon agent for olefin metathesis.
• Authors of publication: Yamamoto, Keishi; Chan, Ka Wing; Mougel, Victor; Nagae, Haruki; Tsurugi, Hayato; Safonova, Olga V.; Mashima, Kazushi; Copéret, Christophe
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 32
• Pages of publication: 3989 - 3992
• a: 16.151 ± 0.005 Å
• b: 27.037 ± 0.008 Å
• c: 16.893 ± 0.005 Å
• α: 90°
• β: 108.232 ± 0.005°
• γ: 90°
• Cell volume: 7006 ± 4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1385
• Residual factor for significantly intense reflections: 0.071
• Weighted residual factors for significantly intense reflections: 0.1184
• Weighted residual factors for all reflections included in the refinement: 0.1423
• Goodness-of-fit parameter for all reflections included in the refinement: 1.049
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No