Information card for entry 7121586

Structure parameters

• Formula: C66 H50 B F24 P Ru
• Calculated formula: C66 H50 B F24 P Ru
• Title of publication: P-C reductive elimination in Ru(ii) complexes to convert triarylphosphine ligands into five- or six-membered phosphacycles.
• Authors of publication: Kuwabara, Takuya; Kato, Takahiro; Takano, Kouichi; Kodama, Shintaro; Manabe, Yuuka; Tsuchida, Noriko; Takano, Keiko; Minami, Yasunori; Hiyama, Tamejiro; Ishii, Youichi
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 42
• Pages of publication: 5357 - 5360
• a: 13.764 ± 0.0016 Å
• b: 17.7878 ± 0.0019 Å
• c: 25.873 ± 0.003 Å
• α: 90°
• β: 103.531 ± 0.002°
• γ: 90°
• Cell volume: 6158.7 ± 1.2 ų
• Cell temperature: 93 ± 2 K
• Ambient diffraction temperature: 93 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0844
• Residual factor for significantly intense reflections: 0.0693
• Weighted residual factors for significantly intense reflections: 0.1624
• Weighted residual factors for all reflections included in the refinement: 0.1737
• Goodness-of-fit parameter for all reflections included in the refinement: 1.091
• Diffraction radiation wavelength: 0.71075 Å
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No