Unexpected behaviour in derivatives of Barluenga's reagent, Hal(Coll)<sub>2</sub>X (Coll = 2,4,6-trimethyl pyridine, collidine; Hal = I, Br; X = PF<sub>6</sub>, ClO<sub>4</sub> & BF<sub>4</sub>).
Authors of publication
Morgan, Lewis C. F.; Kim, Yejin; Blandy, Jack N.; Murray, Claire A.; Christensen, Kirsten E.; Thompson, Amber L.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2018
Journal volume
54
Journal issue
70
Pages of publication
9849 - 9852
a
26.7649 ± 0.0004 Å
b
10.8741 ± 0.0001 Å
c
23.3335 ± 0.0003 Å
α
90°
β
126.93 ± 0.002°
γ
90°
Cell volume
5428.59 ± 0.19 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
6
Space group number
15
Hermann-Mauguin space group symbol
C 1 2/c 1
Hall space group symbol
-C 2yc
Residual factor for all reflections
0.0255
Residual factor for significantly intense reflections
0.025
Weighted residual factors for all reflections
0.0666
Weighted residual factors for significantly intense reflections
0.0662
Weighted residual factors for all reflections included in the refinement
0.0666
Goodness-of-fit parameter for all reflections included in the refinement
