Unexpected behaviour in derivatives of Barluenga's reagent, Hal(Coll)<sub>2</sub>X (Coll = 2,4,6-trimethyl pyridine, collidine; Hal = I, Br; X = PF<sub>6</sub>, ClO<sub>4</sub> & BF<sub>4</sub>).
Authors of publication
Morgan, Lewis C. F.; Kim, Yejin; Blandy, Jack N.; Murray, Claire A.; Christensen, Kirsten E.; Thompson, Amber L.
Journal of publication
Chemical communications (Cambridge, England)
Year of publication
2018
Journal volume
54
Journal issue
70
Pages of publication
9849 - 9852
a
7.9058 ± 0.0003 Å
b
8.2573 ± 0.0003 Å
c
15.1037 ± 0.0006 Å
α
98.632 ± 0.003°
β
98.087 ± 0.003°
γ
100.308 ± 0.003°
Cell volume
944.74 ± 0.06 Å3
Cell temperature
100 K
Ambient diffraction temperature
100 K
Number of distinct elements
6
Space group number
2
Hermann-Mauguin space group symbol
P -1
Hall space group symbol
-P 1
Residual factor for all reflections
0.0283
Residual factor for significantly intense reflections
0.0279
Weighted residual factors for all reflections
0.0747
Weighted residual factors for significantly intense reflections
0.0744
Weighted residual factors for all reflections included in the refinement
0.0747
Goodness-of-fit parameter for all reflections included in the refinement
