Information card for entry 7122362

Structure parameters

• Chemical name: gold3 iminoformyl
• Formula: C82 H106 Au2 N4 O5
• Calculated formula: C82 H108 Au2 N4 O5
• Title of publication: Isocyanide insertion into Au-H bonds: first gold iminoformyl complexes.
• Authors of publication: Fernandez-Cestau, Julio; Rocchigiani, Luca; Pintus, Anna; Rama, Raquel J.; Budzelaar, Peter H. M.; Bochmann, Manfred
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 81
• Pages of publication: 11447 - 11450
• a: 13.7382 ± 0.0004 Å
• b: 33.2731 ± 0.0008 Å
• c: 18.3424 ± 0.0005 Å
• α: 90°
• β: 110.79 ± 0.003°
• γ: 90°
• Cell volume: 7838.6 ± 0.4 ų
• Cell temperature: 140 ± 2 K
• Ambient diffraction temperature: 140 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0775
• Residual factor for significantly intense reflections: 0.067
• Weighted residual factors for significantly intense reflections: 0.1327
• Weighted residual factors for all reflections included in the refinement: 0.137
• Goodness-of-fit parameter for all reflections included in the refinement: 1.332
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No