Information card for entry 7122577

Structure parameters

• Formula: C46 H53 F3 N5 O3 P S Si
• Calculated formula: C46 H53 F3 N5 O3 P S Si
• Title of publication: Taming a silyldiium cation and its reactivity towards sodium phosphaethynolate.
• Authors of publication: Hermannsdorfer, André; Stephan, Douglas W.; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 96
• Pages of publication: 13523 - 13526
• a: 20.7909 ± 0.0002 Å
• b: 9.6113 ± 0.0001 Å
• c: 23.6415 ± 0.0002 Å
• α: 90°
• β: 105.534 ± 0.001°
• γ: 90°
• Cell volume: 4551.66 ± 0.08 ų
• Cell temperature: 150 ± 0.1 K
• Ambient diffraction temperature: 150 ± 0.1 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0607
• Residual factor for significantly intense reflections: 0.055
• Weighted residual factors for significantly intense reflections: 0.1425
• Weighted residual factors for all reflections included in the refinement: 0.1486
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No