Information card for entry 7122629

Structure parameters

• Formula: C16 H16 As4 K10 N16 O10 W6
• Calculated formula: C16 As4 K10 N16 O10 W6
• Title of publication: From oxide to a new type of molecular tungsten compound: formation of bitetrahedral cluster complexes [{W₆(μ₄-O)₂(μ₃-CCN)₄}(CN)₁₆]^10- and [{W₆(μ₄-O)₂(μ₃-As)₄}(CN)₁₆]¹⁰.
• Authors of publication: Yarovoy, Spartak S.; Smolentsev, Anton I.; Kozlova, Svetlana G.; Kompankov, Nikolay B.; Gayfulin, Yakov M.; Asanov, Igor P.; Yanshole, Vadim V.; Mironov, Yuri V.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2018
• Journal volume: 54
• Journal issue: 98
• Pages of publication: 13837 - 13840
• a: 11.844 ± 0.0003 Å
• b: 17.5913 ± 0.0004 Å
• c: 12.0559 ± 0.0003 Å
• α: 90°
• β: 107.084 ± 0.001°
• γ: 90°
• Cell volume: 2401.03 ± 0.1 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0459
• Residual factor for significantly intense reflections: 0.0337
• Weighted residual factors for significantly intense reflections: 0.0759
• Weighted residual factors for all reflections included in the refinement: 0.0798
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No