Information card for entry 7123052

Structure parameters

• Formula: C35 H51 F2 N3 O2 Si3
• Calculated formula: C35 H51 F2 N3 O2 Si3
• Title of publication: Silylene induced cooperative B‒H bond activation and unprecedented aldehyde C‒H bond splitting with amidinate ring expansion
• Authors of publication: Roesky, Herbert W.; Swamy, V S. V. S. N.; Vanka, Kumar; Raj, K. Vipin; Sen, Sakya Singha
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 11.174 ± 0.004 Å
• b: 16.174 ± 0.006 Å
• c: 20.535 ± 0.008 Å
• α: 90°
• β: 101.522 ± 0.009°
• γ: 90°
• Cell volume: 3636 ± 2 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1479
• Residual factor for significantly intense reflections: 0.0693
• Weighted residual factors for significantly intense reflections: 0.0973
• Weighted residual factors for all reflections included in the refinement: 0.1185
• Goodness-of-fit parameter for all reflections included in the refinement: 1.046
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No