Information card for entry 7123417

Structure parameters

• Common name: RJW_NiSiOx
• Chemical name: IPrNiCl(SiMe2(SiMe(SiMe3)2))
• Formula: C36 H63 Cl N2 Ni Si4
• Calculated formula: C36 H63 Cl N2 Ni Si4
• Title of publication: A two-coordinate Ni(I) silyl complex: CO2 insertion and oxidatively-induced silyl migrations
• Authors of publication: Witzke, Ryan J.; Tilley, T. Don
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 16.488 ± 0.002 Å
• b: 18.79 ± 0.003 Å
• c: 27.26 ± 0.006 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 8445 ± 3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.2029
• Residual factor for significantly intense reflections: 0.0831
• Weighted residual factors for significantly intense reflections: 0.1933
• Weighted residual factors for all reflections included in the refinement: 0.2541
• Goodness-of-fit parameter for all reflections included in the refinement: 1.007
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No