Information card for entry 7123739

Structure parameters

• Common name: [(CpAr*)(Cp*)Th(Me3Si-C-CH=CHC-SiMe3)]
• Formula: C95 H140 Si2 Th
• Calculated formula: C95 H140 Si2 Th
• Title of publication: Monomeric Thorium Dihydrido Complex: A Versatile Precursor to Actinide Metallacycles
• Authors of publication: Qin, Guorui; Wang, Yang; Shi, Xianghui; del Rosal, Iker; Laurent, Maron; Cheng, Jianhua
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 15.5087 ± 0.0008 Å
• b: 20.668 ± 0.0011 Å
• c: 30.4806 ± 0.0016 Å
• α: 90°
• β: 101.23 ± 0.001°
• γ: 90°
• Cell volume: 9583 ± 0.9 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193 ± 2 K
• Number of distinct elements: 4
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0721
• Residual factor for significantly intense reflections: 0.0466
• Weighted residual factors for significantly intense reflections: 0.1057
• Weighted residual factors for all reflections included in the refinement: 0.1156
• Goodness-of-fit parameter for all reflections included in the refinement: 0.934
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No