Information card for entry 7124217

Structure parameters

• Formula: C32 H42 N2 O4.5 Rh
• Calculated formula: C32 H37 N2 O4.5 Rh
• Title of publication: Modulation of Coordination Geometry of NCN and NCNC Rh Complexes for Ambidextrous Chiral Catalysts
• Authors of publication: Ito, Jun-ichi; Ishihara, Takahiro; Fukuoka, Takaki; Binti Mat Napi, Siti Rokiah; Kameo, Hajime; Nishiyama, Hisao
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 8.797 ± 0.004 Å
• b: 12.138 ± 0.005 Å
• c: 15.509 ± 0.006 Å
• α: 89.798 ± 0.007°
• β: 86.468 ± 0.007°
• γ: 70.434 ± 0.007°
• Cell volume: 1557.2 ± 1.1 ų
• Cell temperature: 123 ± 2 K
• Ambient diffraction temperature: 123 ± 2 K
• Number of distinct elements: 5
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.0352
• Residual factor for significantly intense reflections: 0.0348
• Weighted residual factors for significantly intense reflections: 0.09
• Weighted residual factors for all reflections included in the refinement: 0.0905
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No