Information card for entry 7124425

Structure parameters

• Formula: C22 H42 Cl N P2 Rh
• Calculated formula: C22 H42 Cl N P2 Rh
• Title of publication: Catalytic reduction of dinitrogen into tris(trimethylsilyl)amine using rhodium complexes with pyrrole-based PNP-type pincer ligand
• Authors of publication: Kawakami, Ryosuke; Kuriyama, Shogo; Tanaka, Hiromasa; Arashiba, Kazuya; Konomi, Asuka; Nakajima, Kazunari; Yoshizawa, Kazunari; Nishibayashi, Yoshiaki
• Journal of publication: Chemical Communications
• Year of publication: 2019
• a: 11.5932 ± 0.0003 Å
• b: 14.511 ± 0.0003 Å
• c: 15.1619 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 2550.67 ± 0.11 ų
• Cell temperature: 173 K
• Ambient diffraction temperature: 173 K
• Number of distinct elements: 6
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0287
• Residual factor for significantly intense reflections: 0.0257
• Weighted residual factors for significantly intense reflections: 0.0574
• Weighted residual factors for all reflections included in the refinement: 0.0583
• Goodness-of-fit parameter for all reflections included in the refinement: 1.056
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No