Information card for entry 7125010

Structure parameters

• Formula: C38 H48 Cl4 I6 P2 Te3
• Calculated formula: C38 H48 Cl4 I6 P2 Te3
• SMILES: [I-][Te](I)(I)(I)([I-])I.[Te]1[P+](c2ccc3c4c(ccc1c24)CC3)(C(C)C)C(C)C.ClCCl.[Te]1[P+](c2ccc3c4c(ccc1c24)CC3)(C(C)C)C(C)C.ClCCl
• Title of publication: Increasing the Brønsted acidity of Ph2PO2H by the Lewis acid B(C6F5)3. Formation of an eight-membered boraphosphinate ring [Ph2POB(C6F5)2O]2.
• Authors of publication: Kather, Ralf; Rychagova, Elena; Sanz Camacho, Paula; Ashbrook, Sharon E.; Woollins, J. Derek; Robben, Lars; Lork, Enno; Ketkov, Sergey; Beckmann, Jens
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 73
• Pages of publication: 10992 - 10995
• a: 22.509 ± 0.004 Å
• b: 11.4213 ± 0.0018 Å
• c: 22.101 ± 0.004 Å
• α: 90°
• β: 110.786 ± 0.002°
• γ: 90°
• Cell volume: 5312 ± 1.6 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for significantly intense reflections: 0.0381
• Weighted residual factors for all reflections included in the refinement: 0.1345
• Goodness-of-fit parameter for all reflections included in the refinement: 1.099
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No