Information card for entry 7125277

Structure parameters

• Common name: chloride-bridge cyclohexyl-Johnphos-gold(I) dimer, SbF6- salt
• Chemical name: mu-chlorobis[(2-biphenyldicyclohexylphosphine)gold(I)] hexafluoroantimonate
• Formula: C50 H66 Au2 Cl3 F6 P2 Sb
• Calculated formula: C50 H66 Au2 Cl3 F6 P2 Sb
• Title of publication: Tetracyclic dihydronaphthalene derivatives via gold-catalyzed aminative homodimerization of ortho-alkynylbenzaldehydes.
• Authors of publication: Ruch, Aaron A.; Kong, Fanji; Nesterov, Vladimir N.; Slaughter, LeGrande M
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2016
• Journal volume: 52
• Journal issue: 98
• Pages of publication: 14133 - 14136
• a: 13.279 ± 0.0006 Å
• b: 14.462 ± 0.0007 Å
• c: 15.6401 ± 0.0012 Å
• α: 100.277 ± 0.001°
• β: 96.426 ± 0.001°
• γ: 115.812 ± 0.001°
• Cell volume: 2598.8 ± 0.3 ų
• Cell temperature: 200 ± 2 K
• Ambient diffraction temperature: 200 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0327
• Residual factor for significantly intense reflections: 0.0291
• Weighted residual factors for significantly intense reflections: 0.0798
• Weighted residual factors for all reflections included in the refinement: 0.0829
• Goodness-of-fit parameter for all reflections included in the refinement: 1.034
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No