Information card for entry 7125630

Structure parameters

• Formula: C94 H90 Li O8 Sn8
• Calculated formula: C90 H87 Li0.5 O6 Sn8
• Title of publication: Reductive dehydrocoupling of diphenyltin dihydride with LiAlH₄: selective synthesis and structures of the first bicyclo[2.2.1]heptastannane-1,4-diide and bicyclo[2.2.2]octastannane-1,4-diide.
• Authors of publication: Steller, Beate G.; Fischer, Roland C.; Flock, Michaela; Hill, Michael S.; Liptrot, David J.; McMullin, Claire L.; Rajabi, Nasir A.; Tiefling, Kathrin; Wilson, Andrew S. S.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 3
• Pages of publication: 336 - 339
• a: 14.2707 ± 0.0006 Å
• b: 14.2569 ± 0.0006 Å
• c: 31.4766 ± 0.0013 Å
• α: 70.797 ± 0.002°
• β: 67.696 ± 0.002°
• γ: 60.735 ± 0.002°
• Cell volume: 5086.5 ± 0.4 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1763
• Residual factor for significantly intense reflections: 0.1291
• Weighted residual factors for significantly intense reflections: 0.3265
• Weighted residual factors for all reflections included in the refinement: 0.3742
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No