Information card for entry 7125810

Structure parameters

• Formula: C34 H56 B10 N4 O2 Si2
• Calculated formula: C34 H56 B10 N4 O2 Si2
• Title of publication: Homocoupling of CO and isocyanide mediated by a C,C'-bis(silylenyl)-substituted ortho-carborane.
• Authors of publication: Xiong, Yun; Yao, Shenglai; Szilvási, Tibor; Ruzicka, Ales; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 5
• Pages of publication: 747 - 750
• a: 14.0023 ± 0.0005 Å
• b: 18.12 ± 0.0008 Å
• c: 19.4694 ± 0.0009 Å
• α: 97.894 ± 0.004°
• β: 110.964 ± 0.004°
• γ: 98.644 ± 0.003°
• Cell volume: 4461.6 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1033
• Residual factor for significantly intense reflections: 0.0573
• Weighted residual factors for significantly intense reflections: 0.1333
• Weighted residual factors for all reflections included in the refinement: 0.1582
• Goodness-of-fit parameter for all reflections included in the refinement: 0.997
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No