Information card for entry 7125878

Structure parameters

• Common name: chiral Ag18S
• Chemical name: Ag18(μ8-S)(p-TBBT)16(PPh3)8
• Formula: C349.68 H478.7 Ag18 O29.68 P8 S17
• Calculated formula: C320 H360 Ag18 P8 S17
• Title of publication: Ag₁₈(μ₈-S)(p-TBBT)₁₆(PPh₃)₈: symmetry breaking induced by the core to generate chirality.
• Authors of publication: Tian, Fan; Chen, Rong
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 18
• Pages of publication: 2719 - 2722
• a: 26.6947 ± 0.0001 Å
• b: 26.6947 ± 0.0001 Å
• c: 50.0946 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 35697.8 ± 0.3 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 6
• Space group number: 130
• Hermann-Mauguin space group symbol: P 4/n c c :2
• Hall space group symbol: -P 4a 2ac
• Residual factor for all reflections: 0.0623
• Residual factor for significantly intense reflections: 0.0552
• Weighted residual factors for significantly intense reflections: 0.1533
• Weighted residual factors for all reflections included in the refinement: 0.1599
• Goodness-of-fit parameter for all reflections included in the refinement: 1.044
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No