Information card for entry 7126625

Structure parameters

• Formula: C21 H39 Au Cl Ge N3 Si2
• Calculated formula: C21 H41 Au Cl Ge N3 Si2
• SMILES: [Au]([Ge]1([N](=C(N1C(C)(C)C)c1ccccc1)C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)Cl
• Title of publication: N-Heterocyclic silylene/germylene ligands in Au(i) catalysis.
• Authors of publication: Parvin, Nasrina; Mishra, Bijoyananda; George, Anjana; Neralkar, Mahesh; Hossain, Jabed; Parameswaran, Pattiyil; Hotha, Srinivas; Khan, Shabana
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 55
• Pages of publication: 7625 - 7628
• a: 8.9235 ± 0.0005 Å
• b: 18.5223 ± 0.0013 Å
• c: 17.845 ± 0.0012 Å
• α: 90°
• β: 101.332 ± 0.002°
• γ: 90°
• Cell volume: 2892 ± 0.3 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0457
• Residual factor for significantly intense reflections: 0.028
• Weighted residual factors for significantly intense reflections: 0.0597
• Weighted residual factors for all reflections included in the refinement: 0.0668
• Goodness-of-fit parameter for all reflections included in the refinement: 1.119
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No