Information card for entry 7126629

Structure parameters

• Formula: C27 H46 Co N3 O Si3
• Calculated formula: C27 H46 Co N3 O Si3
• SMILES: [Co]1234([Si]5([N](=C(N5C(C)(C)C)c5ccccc5)C(C)(C)C)N([Si](C)(C)C)[Si](C)(C)C)([cH]5[cH]3[cH]2[cH]1[cH]45)C#[O]
• Title of publication: N-Heterocyclic silylene/germylene ligands in Au(i) catalysis.
• Authors of publication: Parvin, Nasrina; Mishra, Bijoyananda; George, Anjana; Neralkar, Mahesh; Hossain, Jabed; Parameswaran, Pattiyil; Hotha, Srinivas; Khan, Shabana
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 55
• Pages of publication: 7625 - 7628
• a: 9.741 ± 0.009 Å
• b: 17.157 ± 0.015 Å
• c: 18.969 ± 0.015 Å
• α: 102.473 ± 0.013°
• β: 91.56 ± 0.02°
• γ: 91.73 ± 0.02°
• Cell volume: 3092 ± 5 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.1738
• Residual factor for significantly intense reflections: 0.1474
• Weighted residual factors for significantly intense reflections: 0.3961
• Weighted residual factors for all reflections included in the refinement: 0.4128
• Goodness-of-fit parameter for all reflections included in the refinement: 1.696
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No