Information card for entry 7126700

Structure parameters

• Formula: C41 H47 N2 O3 P2 Rh
• Calculated formula: C41 H47 N2 O3 P2 Rh
• SMILES: C1N([P+](C([P+](N2CCCCC2)(c2ccccc2)c2ccccc2)=[Rh]2(OC(=CC(=[O]2)C)C)C#[O])(c2ccccc2)c2ccccc2)CCCC1
• Title of publication: A diamino-substituted carbodiphosphorane as strong C-donor and weak N-donor: isolation of monomeric trigonal-planar L·ZnCl₂.
• Authors of publication: Kroll, Alexander; Steinert, Henning; Scharf, Lennart T.; Scherpf, Thorsten; Mallick, Bert; Gessner, Viktoria H.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 58
• Pages of publication: 8051 - 8054
• a: 14.0618 ± 0.0002 Å
• b: 16.9278 ± 0.0003 Å
• c: 19.7394 ± 0.0003 Å
• α: 88.863 ± 0.001°
• β: 89.772 ± 0.001°
• γ: 77.86 ± 0.001°
• Cell volume: 4592.69 ± 0.13 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.045
• Residual factor for significantly intense reflections: 0.042
• Weighted residual factors for significantly intense reflections: 0.1172
• Weighted residual factors for all reflections included in the refinement: 0.1198
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No