Information card for entry 7127422

Structure parameters

• Formula: C25 H42 Cl2 Ge N2 P2 Pd
• Calculated formula: C25 H42 Cl2 Ge N2 P2 Pd
• SMILES: CC(C)[P]1(C(C)C)Cc2ccc3C(C)(C)c4ccc5C[P](C(C)C)(C(C)C)[Pd]1(Cl)[Ge](Cl)(n23)n45
• Title of publication: A Z-type PGeP pincer germylene ligand in a T-shaped palladium(0) complex.
• Authors of publication: Cabeza, Javier A.; García-Álvarez, Pablo; Laglera-Gándara, Carlos J; Pérez-Carreño, Enrique
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2020
• Journal volume: 56
• Journal issue: 90
• Pages of publication: 14095 - 14097
• a: 11.496 ± 0.0002 Å
• b: 18.413 ± 0.0003 Å
• c: 14.671 ± 0.0003 Å
• α: 90°
• β: 106.665 ± 0.002°
• γ: 90°
• Cell volume: 2975.06 ± 0.1 ų
• Cell temperature: 140 ± 2 K
• Ambient diffraction temperature: 140 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0392
• Residual factor for significantly intense reflections: 0.0363
• Weighted residual factors for significantly intense reflections: 0.0957
• Weighted residual factors for all reflections included in the refinement: 0.0998
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 1.5418 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No