Information card for entry 7127717

Structure parameters

• Formula: C18 H48 N8 O8.5 Pd Rh2 S6
• Calculated formula: C18 H48 N8 O8.5 Pd Rh2 S6
• Title of publication: Interconversion between square-planar palladium(ii) and octahedral palladium(iv) centres in a sulfur-bridged trinuclear structure.
• Authors of publication: Kouno, Masahiro; Kuwamura, Naoto; Konno, Takumi
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2021
• Journal volume: 57
• Journal issue: 11
• Pages of publication: 1336 - 1339
• a: 9.5252 ± 0.0012 Å
• b: 13.7778 ± 0.0018 Å
• c: 27.631 ± 0.004 Å
• α: 102.207 ± 0.007°
• β: 96.462 ± 0.007°
• γ: 98.213 ± 0.007°
• Cell volume: 3469.4 ± 0.8 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.2074
• Residual factor for significantly intense reflections: 0.1011
• Weighted residual factors for significantly intense reflections: 0.228
• Weighted residual factors for all reflections included in the refinement: 0.2887
• Goodness-of-fit parameter for all reflections included in the refinement: 1.04
• Diffraction radiation wavelength: 0.7004 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No