Information card for entry 7128277

Structure parameters

• Chemical name: (N,N-bis(2-(diphenylphosphinomethylamido)phenyl)methylamine)-(dimethyl(phenyl)silyl)-(μ-pyridin-2-yl)-aluminium-rhodium
• Formula: C52 H50 Al N4 P2 Rh Si
• Calculated formula: C52 H50 Al N4 P2 Rh Si
• SMILES: [Rh]123([P](c4ccccc4)(c4ccccc4)CN4[Al]52(N(c2c([N]5(c5c4cccc5)C)cccc2)C[P]1(c1ccccc1)c1ccccc1)[n]1ccccc31)[Si](C)(c1ccccc1)C
• Title of publication: C2-Selective silylation of pyridines by a rhodium-aluminum complex.
• Authors of publication: Hara, Naofumi; Uemura, Nao; Nakao, Yoshiaki
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2021
• Journal volume: 57
• Journal issue: 48
• Pages of publication: 5957 - 5960
• a: 29.694 ± 0.005 Å
• b: 10.5922 ± 0.0016 Å
• c: 32.967 ± 0.005 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 10369 ± 3 ų
• Cell temperature: 143.15 K
• Ambient diffraction temperature: 143.15 K
• Number of distinct elements: 7
• Space group number: 61
• Hermann-Mauguin space group symbol: P b c a
• Hall space group symbol: -P 2ac 2ab
• Residual factor for all reflections: 0.0797
• Residual factor for significantly intense reflections: 0.0611
• Weighted residual factors for significantly intense reflections: 0.1147
• Weighted residual factors for all reflections included in the refinement: 0.1239
• Goodness-of-fit parameter for all reflections included in the refinement: 1.094
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No