Information card for entry 7128322

Structure parameters

• Formula: C29 H60 B10 N4 O2.5 P Si
• Calculated formula: C29 H60 B10 N4 O2.5 P Si
• Title of publication: Distinctly different reactivity of bis(silylenyl)-<i>versus</i> phosphanyl-silylenyl-substituted <i>o</i>-dicarborane towards O₂, N₂O and CO₂.
• Authors of publication: Xiong, Yun; Yao, Shenglai; Ruzicka, Ales; Driess, Matthias
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2021
• Journal volume: 57
• Journal issue: 48
• Pages of publication: 5965 - 5968
• a: 33.177 ± 0.0009 Å
• b: 10.4724 ± 0.0003 Å
• c: 22.8239 ± 0.0006 Å
• α: 90°
• β: 100.412 ± 0.003°
• γ: 90°
• Cell volume: 7799.4 ± 0.4 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.1325
• Residual factor for significantly intense reflections: 0.0668
• Weighted residual factors for significantly intense reflections: 0.1418
• Weighted residual factors for all reflections included in the refinement: 0.1823
• Goodness-of-fit parameter for all reflections included in the refinement: 1.027
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No