Information card for entry 7129959

Structure parameters

• Formula: C52 H52 F10 K N2 O Si Zn
• Calculated formula: C52 H52 F10 K N2 O Si Zn
• Title of publication: Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand
• Authors of publication: Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva
• Journal of publication: Chemical Communications
• Year of publication: 2022
• a: 10.92365 ± 0.00017 Å
• b: 15.318 ± 0.0004 Å
• c: 15.4312 ± 0.0002 Å
• α: 86.8366 ± 0.0016°
• β: 86.8944 ± 0.0013°
• γ: 72.2944 ± 0.0017°
• Cell volume: 2454.12 ± 0.08 ų
• Cell temperature: 173 ± 0.1 K
• Ambient diffraction temperature: 173 ± 0.1 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0716
• Residual factor for significantly intense reflections: 0.0659
• Weighted residual factors for significantly intense reflections: 0.195
• Weighted residual factors for all reflections included in the refinement: 0.2012
• Goodness-of-fit parameter for all reflections included in the refinement: 1.054
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No