Information card for entry 7129965

Structure parameters

• Formula: C70 H103 F K N3 O9 Si Zn
• Calculated formula: C70 H103 F K N3 O9 Si Zn
• Title of publication: Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand
• Authors of publication: Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva
• Journal of publication: Chemical Communications
• Year of publication: 2022
• a: 22.63 ± 0.003 Å
• b: 15.765 ± 0.001 Å
• c: 20.4853 ± 0.0017 Å
• α: 90°
• β: 108.879 ± 0.012°
• γ: 90°
• Cell volume: 6915.2 ± 1.3 ų
• Cell temperature: 84.8 ± 0.6 K
• Ambient diffraction temperature: 84.8 ± 0.6 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.151
• Residual factor for significantly intense reflections: 0.1316
• Weighted residual factors for significantly intense reflections: 0.3393
• Weighted residual factors for all reflections included in the refinement: 0.358
• Goodness-of-fit parameter for all reflections included in the refinement: 1.035
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No