Information card for entry 7129968

Structure parameters

• Formula: C110 H152 F4 K2 N4 O8 Si2 Zn2
• Calculated formula: C110 H152 F4 K2 N4 O8 Si2 Zn2
• Title of publication: Metallation of sensitive fluoroarenes using a potassium TMP-zincate supported by a silyl(bis)amido ligand
• Authors of publication: Mastropierro, Pasquale; Kennedy, Alan R.; Hevia, Eva
• Journal of publication: Chemical Communications
• Year of publication: 2022
• a: 12.14746 ± 0.00007 Å
• b: 29.80377 ± 0.00015 Å
• c: 15.17589 ± 0.00008 Å
• α: 90°
• β: 105.049 ± 0.0006°
• γ: 90°
• Cell volume: 5305.84 ± 0.05 ų
• Cell temperature: 100.01 ± 0.1 K
• Ambient diffraction temperature: 100.01 ± 0.1 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0372
• Residual factor for significantly intense reflections: 0.0359
• Weighted residual factors for significantly intense reflections: 0.0965
• Weighted residual factors for all reflections included in the refinement: 0.0975
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No