Information card for entry 7131274

Structure parameters

• Formula: C103 H101 Al F36 O9 P2 Rh
• Calculated formula: C103 H101 Al F36 O9 P2 Rh
• Title of publication: Synthesis of a rhodium(III) dinitrogen complex using a calix[4]arene-based diphosphine ligand.
• Authors of publication: Emerson-King, Jack; Pan, Sudip; Gyton, Matthew R.; Tonner-Zech, Ralf; Chaplin, Adrian B.
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2023
• Journal volume: 59
• Journal issue: 15
• Pages of publication: 2150 - 2152
• a: 15.5193 ± 0.0003 Å
• b: 18.998 ± 0.0004 Å
• c: 20.2822 ± 0.0003 Å
• α: 68.8958 ± 0.0017°
• β: 81.7243 ± 0.0014°
• γ: 69.6826 ± 0.0019°
• Cell volume: 5230.51 ± 0.19 ų
• Cell temperature: 150 ± 2 K
• Ambient diffraction temperature: 150 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0544
• Residual factor for significantly intense reflections: 0.0446
• Weighted residual factors for significantly intense reflections: 0.1192
• Weighted residual factors for all reflections included in the refinement: 0.1282
• Goodness-of-fit parameter for all reflections included in the refinement: 1.042
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No