Information card for entry 7132375

Structure parameters

• Formula: C206.25 H152 Cl2 N4 O8 P4 Rh2
• Calculated formula: C206.25 H152 Cl2 N4 O8 P4 Rh2
• Title of publication: Evolution of a 'privileged' P-alkene ligand: added planar chirality beats BINOL axial chirality in catalytic asymmetric C-C bond formation.
• Authors of publication: Leinauer, Luisa; Parla, Giorgio; Messelbeger, Julian; Herrera, Alberto; Heinemann, Frank W.; Langer, Jens; Chuchelkin, Ilya; Grasruck, Alexander; Frieß, Sibylle; Chelouan, Ahmed; Gavrilov, Konstantin; Dorta, Romano
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2023
• a: 17.4039 ± 0.0012 Å
• b: 19.9901 ± 0.0014 Å
• c: 25.7764 ± 0.0017 Å
• α: 67.834 ± 0.002°
• β: 80.669 ± 0.003°
• γ: 76.916 ± 0.003°
• Cell volume: 8060.1 ± 1 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 1
• Hermann-Mauguin space group symbol: P 1
• Hall space group symbol: P 1
• Residual factor for all reflections: 0.072
• Residual factor for significantly intense reflections: 0.051
• Weighted residual factors for significantly intense reflections: 0.1072
• Weighted residual factors for all reflections included in the refinement: 0.117
• Goodness-of-fit parameter for all reflections included in the refinement: 1.036
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No