Information card for entry 7133147

Structure parameters

• Formula: C89.36 H97.27 B F24 N2 O3 P Si
• Calculated formula: C89.364 H97.272 B F24 N2 O3 P Si
• Title of publication: P(V)-bis(amidophenolate) ligand cooperation: Stoichiometric C=O-bond cleavage in aldehydes and ketones
• Authors of publication: Karnbrock, Simon Bernhard Hugo; Golz, Christopher; Alcarazo, Manuel
• Journal of publication: Chemical Communications
• Year of publication: 2024
• a: 13.1456 ± 0.0007 Å
• b: 17.6698 ± 0.0012 Å
• c: 20.0734 ± 0.0015 Å
• α: 95.272 ± 0.002°
• β: 103.875 ± 0.002°
• γ: 91.26 ± 0.002°
• Cell volume: 4502.8 ± 0.5 ų
• Cell temperature: 100 K
• Ambient diffraction temperature: 100 K
• Number of distinct elements: 8
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0714
• Residual factor for significantly intense reflections: 0.0534
• Weighted residual factors for significantly intense reflections: 0.1375
• Weighted residual factors for all reflections included in the refinement: 0.1511
• Goodness-of-fit parameter for all reflections included in the refinement: 1.072
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No