Information card for entry 7133210

Structure parameters

• Common name: diphenyl (10H-5l5-5,10-[1,2]benzenoacridophosphin-5-ylidene)phosphoramidate
• Chemical name: diphenyl (10H-5l5-5,10-[1,2]benzenoacridophosphin-5-ylidene)phosphoramidate
• Formula: C31 H23 N O3 P2
• Calculated formula: C31 H23 N O3 P2
• Title of publication: Regulating iminophosphorane PN bond reactivity through geometric constraints with cage-shaped triarylphosphines.
• Authors of publication: Hu, Lei; Chakraborty, Sayandip; Tumanov, Nikolay; Wouters, Johan; Robiette, Raphaël; Berionni, Guillaume
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• a: 11.81181 ± 0.00013 Å
• b: 19.91502 ± 0.00017 Å
• c: 11.98573 ± 0.00013 Å
• α: 90°
• β: 118.939 ± 0.0015°
• γ: 90°
• Cell volume: 2467.38 ± 0.06 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0342
• Residual factor for significantly intense reflections: 0.0316
• Weighted residual factors for significantly intense reflections: 0.0812
• Weighted residual factors for all reflections included in the refinement: 0.0834
• Goodness-of-fit parameter for all reflections included in the refinement: 1.009
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No