Information card for entry 7133685

Structure parameters

• Formula: C45 H70 Mg N2 Si
• Calculated formula: C45 H70 Mg N2 Si
• Title of publication: A series of neutral alkaline earth metal hydride complexes supported by a bulky, unsymmetrical β-diketiminate ligand, [{(^Dip/TCHPNacnac)M(μ-H)}₂] (M = Mg, Ca, Sr or Ba).
• Authors of publication: Kennedy, Dominic B.; Evans, Matthew J.; Jones, Dafydd D. L.; Parr, Joseph M.; Hill, Michael S.; Jones, Cameron
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 78
• Pages of publication: 10894 - 10897
• a: 17.7 ± 0.004 Å
• b: 13.92 ± 0.003 Å
• c: 18.7 ± 0.004 Å
• α: 90°
• β: 114.08 ± 0.03°
• γ: 90°
• Cell volume: 4206.4 ± 1.9 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 5
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/n 1
• Hall space group symbol: -P 2yn
• Residual factor for all reflections: 0.0403
• Residual factor for significantly intense reflections: 0.0383
• Weighted residual factors for significantly intense reflections: 0.1041
• Weighted residual factors for all reflections included in the refinement: 0.1057
• Goodness-of-fit parameter for all reflections included in the refinement: 1.024
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: Synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No