Information card for entry 7133909

Structure parameters

• Formula: C19 H22 O S Si
• Calculated formula: C19 H22 O S Si
• Title of publication: Rhodium-catalyzed synthesis of Si-stereogenic alkoxysilanes and silyl enol ethers <i>via</i> hydrosilylation of carbonyl compounds.
• Authors of publication: Ding, Yang; Ke, Jie; Zhang, Wenbin; Li, Bin; He, Chuan
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2024
• Journal volume: 60
• Journal issue: 93
• Pages of publication: 13734 - 13737
• a: 6.013 ± 0.0002 Å
• b: 16.5709 ± 0.0004 Å
• c: 17.6278 ± 0.0004 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 1756.45 ± 0.08 ų
• Cell temperature: 100 ± 0.2 K
• Ambient diffraction temperature: 100 ± 0.2 K
• Number of distinct elements: 5
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.0295
• Residual factor for significantly intense reflections: 0.0293
• Weighted residual factors for significantly intense reflections: 0.0758
• Weighted residual factors for all reflections included in the refinement: 0.0759
• Goodness-of-fit parameter for all reflections included in the refinement: 1.125
• Diffraction radiation probe: x-ray
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No