Information card for entry 7134129

Structure parameters

• Formula: C54 H53 Mn N2 O5 P Rh
• Calculated formula: C54 H53 Mn N2 O5 P Rh
• Title of publication: Pushing the limits of electron donation for <i>cis</i>-chelating ligands <i>via</i> an alliance of phosphonium ylide and anionic abnormal NHC.
• Authors of publication: El Kadiri, Mustapha; Cherradi, Abdelhaq; Filippov, Oleg A.; Duhayon, Carine; César, Vincent; Shubina, Elena S.; Lahcini, Mohammed; Valyaev, Dmitry A.; Canac, Yves
• Journal of publication: Chemical communications (Cambridge, England)
• Year of publication: 2025
• Journal volume: 61
• Journal issue: 13
• Pages of publication: 2778 - 2781
• a: 12.5157 ± 0.0001 Å
• b: 14.6557 ± 0.0002 Å
• c: 15.2251 ± 0.0002 Å
• α: 107.403 ± 0.001°
• β: 110.853 ± 0.001°
• γ: 94.571 ± 0.001°
• Cell volume: 2435.42 ± 0.06 ų
• Cell temperature: 100 ± 2 K
• Ambient diffraction temperature: 100 ± 2 K
• Number of distinct elements: 7
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0329
• Residual factor for significantly intense reflections: 0.031
• Weighted residual factors for significantly intense reflections: 0.0843
• Weighted residual factors for all reflections included in the refinement: 0.0852
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No