Information card for entry 7151170

Structure parameters

• Formula: C42 H34 Cl2 N2 O6 P2 Pt
• Calculated formula: C42 H30 Cl2 N2 O6 P2 Pt
• SMILES: O.O.[Pt]1(Cl)(Cl)[P]2(N(N([P]31Oc1ccc4ccccc4c1c1c4ccccc4ccc1O3)C)C)Oc1ccc3ccccc3c1c1c3ccccc3ccc1O2
• Title of publication: Efficient asymmetric hydrogenation of olefins with hydrazine-derived diphosphoramidites.
• Authors of publication: Eberhardt, Luc; Armspach, Dominique; Matt, Dominique; Oswald, Benoît; Toupet, Loic
• Journal of publication: Organic & biomolecular chemistry
• Year of publication: 2007
• Journal volume: 5
• Journal issue: 20
• Pages of publication: 3340 - 3346
• a: 11.1024 ± 0.0004 Å
• b: 13.8168 ± 0.0005 Å
• c: 26.9261 ± 0.0009 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4130.5 ± 0.3 ų
• Cell temperature: 295 ± 2 K
• Ambient diffraction temperature: 293 ± 2 K
• Number of distinct elements: 7
• Space group number: 19
• Hermann-Mauguin space group symbol: P 21 21 21
• Hall space group symbol: P 2ac 2ab
• Residual factor for all reflections: 0.051
• Residual factor for significantly intense reflections: 0.0422
• Weighted residual factors for significantly intense reflections: 0.1143
• Weighted residual factors for all reflections included in the refinement: 0.1181
• Goodness-of-fit parameter for all reflections included in the refinement: 1.03
• Diffraction radiation wavelength: 0.71069 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No