Information card for entry 7217986

Structure parameters

• Chemical name: Dibromo(1,2-bis(dimethylphosphino)benzene-P,P')germanium(II)
• Formula: C10 H16 Br2 Ge P2
• Calculated formula: C10 H16 Br2 Ge P2
• SMILES: C[P]1(C)c2ccccc2[P](C)(C)[Ge]1Br.[Br-]
• Title of publication: Exploring secondary bonding in p-block chemistry ‒ an experimental study of [GeX2{o-C6H4(PMe2)2}] using variable pressure single crystal X-ray diffraction
• Authors of publication: Allan, David R.; Coles, Simon J.; George, Kathryn; Jura, Marek; Levason, William; Reid, Gillian; Wilson, Claire; Zhang, Wenjian
• Journal of publication: CrystEngComm
• Year of publication: 2014
• Journal volume: 16
• Journal issue: 35
• Pages of publication: 8169
• a: 25.79 ± 0.1 Å
• b: 7.17 ± 0.03 Å
• c: 14.06 ± 0.05 Å
• α: 90°
• β: 92.24 ± 0.08°
• γ: 90°
• Cell volume: 2598 ± 17 ų
• Cell temperature: 293 ± 2 K
• Ambient diffraction temperature: 293 K
• Cell measurement pressure: 4100000 kPa
• Ambient diffracton pressure: 4100000 kPa
• Number of distinct elements: 5
• Space group number: 15
• Hermann-Mauguin space group symbol: C 1 2/c 1
• Hall space group symbol: -C 2yc
• Residual factor for all reflections: 0.178
• Residual factor for significantly intense reflections: 0.1146
• Weighted residual factors for significantly intense reflections: 0.2847
• Weighted residual factors for all reflections included in the refinement: 0.3481
• Goodness-of-fit parameter for all reflections included in the refinement: 1.106
• Diffraction radiation wavelength: 0.6889 Å
• Diffraction radiation type: synchrotron
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No