Information card for entry 7218787

Structure parameters

• Chemical name: [Pt(bpy){NH=C(pz)NC(Me)=NH}]PF6
• Formula: C16 H16 F6 N7 P Pt
• Calculated formula: C16 H16 F6 N7 P Pt
• SMILES: [Pt]12([n]3c(c4[n]2cccc4)cccc3)NC(=NC(=[NH]1)C)n1nccc1.[P](F)(F)(F)(F)(F)[F-]
• Title of publication: Highly luminescent imidoylamidinato platinum(ii) complexes formed by the coupling of 1H-pyrazole-1-carboxamidine with nitriles used as reaction solvents
• Authors of publication: Tanaka, Tomohiro; Nouchi, Rie; Nakao, Yoshihide; Arikawa, Yasuhiro; Umakoshi, Keisuke
• Journal of publication: RSC Adv.
• Year of publication: 2014
• Journal volume: 4
• Journal issue: 107
• Pages of publication: 62186
• a: 7.05 ± 0.003 Å
• b: 21.06 ± 0.009 Å
• c: 13.409 ± 0.007 Å
• α: 90°
• β: 104.882 ± 0.008°
• γ: 90°
• Cell volume: 1924.1 ± 1.5 ų
• Cell temperature: 93 K
• Ambient diffraction temperature: 93 K
• Number of distinct elements: 6
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for significantly intense reflections: 0.0326
• Weighted residual factors for all reflections included in the refinement: 0.0749
• Goodness-of-fit parameter for all reflections included in the refinement: 0.971
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: No
• Has Fobs: No