Information card for entry 7224478

Structure parameters

• Chemical name: (3R*,4R*,5R*)-5-phenyl-3-(triisopropylsilyloxy)-4-vinyldihydrofuran-2(3H)-one
• Formula: C41.5 H61.5 O6 Si2
• Calculated formula: C41.471 H61.413 O6 Si2
• Title of publication: Reverse regioselectivity in Pd(0)/InI-mediated allylation of aldehydes with ε-amido-allylindiums generated from β-lactams. A new entry to non-racemic highly substituted γ-butyrolactones.
• Authors of publication: Klimczak, Urszula Katarzyna; Staszewska-Krajewska, Olga; Zambroń, Bartosz Krzysztof
• Journal of publication: RSC Adv.
• Year of publication: 2016
• a: 11.9536 ± 0.0005 Å
• b: 13.6314 ± 0.0006 Å
• c: 13.8816 ± 0.0006 Å
• α: 84.881 ± 0.003°
• β: 77.283 ± 0.003°
• γ: 88.864 ± 0.003°
• Cell volume: 2197.64 ± 0.17 ų
• Cell temperature: 296 ± 2 K
• Ambient diffraction temperature: 296 ± 2 K
• Number of distinct elements: 4
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.096
• Residual factor for significantly intense reflections: 0.066
• Weighted residual factors for significantly intense reflections: 0.2084
• Weighted residual factors for all reflections included in the refinement: 0.2315
• Goodness-of-fit parameter for all reflections included in the refinement: 1.109
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No