Synthesis, Crystal Structure and Hydrolysis of Novel Isomeric Cage (P‒C/P‒O)-Phosphoranes on the basis of 4,4,5,5-Tetramethyl-2-(2-oxo-1,2-diphenylethoxy)-1,3,2-dioxaphospholane and Hexafluoroacetone
Authors of publication
Khasiyatullina, Nadezhda; Mironov, Vladimir Fedorovich; Krivolapov, Dmitry; Mironova, Ekaterina V.; Gnezdilov, Oleg I.
Journal of publication
RSC Adv.
Year of publication
2016
a
18.721 ± 0.008 Å
b
13.944 ± 0.006 Å
c
8.706 ± 0.004 Å
α
90°
β
95.489 ± 0.008°
γ
90°
Cell volume
2262.2 ± 1.7 Å3
Cell temperature
296 ± 2 K
Ambient diffraction temperature
296 ± 2 K
Number of distinct elements
5
Space group number
14
Hermann-Mauguin space group symbol
P 1 21/c 1
Hall space group symbol
-P 2ybc
Residual factor for all reflections
0.2229
Residual factor for significantly intense reflections
0.0773
Weighted residual factors for significantly intense reflections
0.1632
Weighted residual factors for all reflections included in the refinement
0.2372
Goodness-of-fit parameter for all reflections included in the refinement
