Information card for entry 7247435

Structure parameters

• Formula: C42 H31 B2 Co F8 N9
• Calculated formula: C42 H31 B2 Co F8 N9
• Title of publication: Homoleptic octahedral CoII complexes as precatalysts for regioselective hydroboration of alkenes with high turnover frequencies
• Authors of publication: Zhang, Guoqi; Zeng, Haisu; Zadori, Nora; Marino, Camila; Zheng, Shengping; Neary, Michelle C.
• Journal of publication: RSC Advances
• Year of publication: 2023
• Journal volume: 13
• Journal issue: 40
• Pages of publication: 28089 - 28096
• a: 8.7498 ± 0.0003 Å
• b: 25.9051 ± 0.0008 Å
• c: 8.5927 ± 0.0003 Å
• α: 90°
• β: 90.761 ± 0.002°
• γ: 90°
• Cell volume: 1947.49 ± 0.11 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 7
• Hermann-Mauguin space group symbol: P 1 c 1
• Hall space group symbol: P -2yc
• Residual factor for all reflections: 0.0613
• Residual factor for significantly intense reflections: 0.0553
• Weighted residual factors for significantly intense reflections: 0.1335
• Weighted residual factors for all reflections included in the refinement: 0.1373
• Goodness-of-fit parameter for all reflections included in the refinement: 1.073
• Diffraction radiation wavelength: 1.54178 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No