Information card for entry 7249442

Structure parameters

• Formula: C32 H45 F6 N11 P Pt2 Rh S2
• Calculated formula: C26 H36 F6 N8 P Pt2 Rh S2
• Title of publication: Restriction of reaction sites on metal-sulfide cores induced by steric repulsion of bis-N-heterocyclic carbene ligands in trinuclear complexes bearing triply bridging sulfide ligands.
• Authors of publication: Yabune, Natsuki; Nakajima, Hiroshi; Nishioka, Takanori
• Journal of publication: RSC advances
• Year of publication: 2024
• Journal volume: 14
• Journal issue: 40
• Pages of publication: 29355 - 29367
• a: 12.3687 ± 0.0011 Å
• b: 12.3687 ± 0.0011 Å
• c: 27.8127 ± 0.0018 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 4254.9 ± 0.6 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193.35 K
• Number of distinct elements: 8
• Space group number: 80
• Hermann-Mauguin space group symbol: I 41
• Hall space group symbol: I 4bw
• Residual factor for all reflections: 0.0555
• Residual factor for significantly intense reflections: 0.0492
• Weighted residual factors for significantly intense reflections: 0.1122
• Weighted residual factors for all reflections included in the refinement: 0.1169
• Goodness-of-fit parameter for all reflections included in the refinement: 1.0062
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No