Information card for entry 7249445

Structure parameters

• Formula: C79 H85 B2 Cl6 N8 Pt2 Rh S2
• Calculated formula: C76 H79 B2 N8 Pt2 Rh S2
• Title of publication: Restriction of reaction sites on metal-sulfide cores induced by steric repulsion of bis-N-heterocyclic carbene ligands in trinuclear complexes bearing triply bridging sulfide ligands.
• Authors of publication: Yabune, Natsuki; Nakajima, Hiroshi; Nishioka, Takanori
• Journal of publication: RSC advances
• Year of publication: 2024
• Journal volume: 14
• Journal issue: 40
• Pages of publication: 29355 - 29367
• a: 17.827 ± 0.004 Å
• b: 25.802 ± 0.004 Å
• c: 13.476 ± 0.003 Å
• α: 90°
• β: 128.641 ± 0.005°
• γ: 90°
• Cell volume: 4841.6 ± 1.7 ų
• Cell temperature: 193 ± 2 K
• Ambient diffraction temperature: 193.35 K
• Number of distinct elements: 8
• Space group number: 8
• Hermann-Mauguin space group symbol: C 1 m 1
• Hall space group symbol: C -2y
• Residual factor for all reflections: 0.0447
• Residual factor for significantly intense reflections: 0.0399
• Weighted residual factors for significantly intense reflections: 0.0958
• Weighted residual factors for all reflections included in the refinement: 0.102
• Goodness-of-fit parameter for all reflections included in the refinement: 0.8978
• Diffraction radiation wavelength: 0.71075 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No