Information card for entry 7249903

Structure parameters

• Chemical name: [N'-(2-oxobenzylidene)isonicotinoylhydrazonato](methoxo)oxovanadium(v) methanol solvate
• Formula: C28.5 H26 N6 O8.5 V2
• Calculated formula: C28 H24 N6 O8 V2
• Title of publication: High-valent oxovanadium metallosupramolecular species as catalysts for the oxidation of benzyl alcohol derivatives.
• Authors of publication: Topić, Edi; Sarjanović, Josipa; Musija, Danijela; Mandarić, Mirna; Hrenar, Tomica; Pisk, Jana; Vrdoljak, Višnja
• Journal of publication: RSC advances
• Year of publication: 2025
• Journal volume: 15
• Journal issue: 5
• Pages of publication: 3547 - 3561
• a: 22.0687 ± 0.0002 Å
• b: 20.5886 ± 0.0002 Å
• c: 26.842 ± 0.0003 Å
• α: 90°
• β: 90°
• γ: 90°
• Cell volume: 12196 ± 0.2 ų
• Cell temperature: 169.98 ± 0.1 K
• Ambient diffraction temperature: 170.15 K
• Number of distinct elements: 5
• Space group number: 73
• Hermann-Mauguin space group symbol: I b c a
• Hall space group symbol: -I 2b 2c
• Residual factor for all reflections: 0.0377
• Residual factor for significantly intense reflections: 0.0352
• Weighted residual factors for significantly intense reflections: 0.0999
• Weighted residual factors for all reflections included in the refinement: 0.1018
• Goodness-of-fit parameter for all reflections included in the refinement: 1.092
• Diffraction radiation wavelength: 1.54184 Å
• Diffraction radiation type: CuKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No