Information card for entry 7700123

Structure parameters

• Formula: C43 H47 Mg N P2 Si2
• Calculated formula: C43 H47 Mg N P2 Si2
• Title of publication: Reactivity of the carbodiphosphorane, (Ph₃P)₂C, towards main group metal alkyl compounds: coordination and cyclometalation.
• Authors of publication: Quinlivan, Patrick J.; Shlian, Daniel G.; Amemiya, Erika; Parkin, Gerard
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 25
• Pages of publication: 9139 - 9151
• a: 10.927 ± 0.002 Å
• b: 13.208 ± 0.002 Å
• c: 14.974 ± 0.003 Å
• α: 87.327 ± 0.003°
• β: 83.015 ± 0.003°
• γ: 73.912 ± 0.003°
• Cell volume: 2060.9 ± 0.6 ų
• Cell temperature: 130 ± 2 K
• Ambient diffraction temperature: 130 ± 2 K
• Number of distinct elements: 6
• Space group number: 2
• Hermann-Mauguin space group symbol: P -1
• Hall space group symbol: -P 1
• Residual factor for all reflections: 0.0646
• Residual factor for significantly intense reflections: 0.0548
• Weighted residual factors for significantly intense reflections: 0.1479
• Weighted residual factors for all reflections included in the refinement: 0.1513
• Goodness-of-fit parameter for all reflections included in the refinement: 1.953
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No