Information card for entry 7700470

Structure parameters

• Common name: Ag[(Xbic)SiPh] . 3 CD2Cl2
• Chemical name: Silver((9,9-dimethylxanthene-4,5-bis(4,6-di-tert-butyl-2,3-dioxybenzaldimine)(phenyl)silicate) tris(deuteriodichloromethane) solvate
• Formula: C54 H57 Ag Cl6 D6 N2 O5 Si
• Calculated formula: C54 H57 Ag Cl6 D6 N2 O5 Si
• Title of publication: Mono- and bimetallic pentacoordinate silicon complexes of a chelating bis(catecholimine) ligand.
• Authors of publication: Do, Thomas H.; Brown, Seth N.
• Journal of publication: Dalton transactions (Cambridge, England : 2003)
• Year of publication: 2019
• Journal volume: 48
• Journal issue: 30
• Pages of publication: 11565 - 11574
• a: 15.9942 ± 0.0018 Å
• b: 19.485 ± 0.002 Å
• c: 17.562 ± 0.002 Å
• α: 90°
• β: 92.0777 ± 0.0016°
• γ: 90°
• Cell volume: 5469.5 ± 1 ų
• Cell temperature: 120 ± 2 K
• Ambient diffraction temperature: 120 ± 2 K
• Number of distinct elements: 8
• Space group number: 14
• Hermann-Mauguin space group symbol: P 1 21/c 1
• Hall space group symbol: -P 2ybc
• Residual factor for all reflections: 0.0674
• Residual factor for significantly intense reflections: 0.0603
• Weighted residual factors for significantly intense reflections: 0.1702
• Weighted residual factors for all reflections included in the refinement: 0.1773
• Goodness-of-fit parameter for all reflections included in the refinement: 1.116
• Diffraction radiation wavelength: 0.71073 Å
• Diffraction radiation type: MoKα
• Has coordinates: Yes
• Has disorder: Yes
• Has Fobs: No